Methods
Datasets
The best reference is Pandora, but comparing to TropOMI is a useful benchmark.
The L2 variables include tropospheric column nitrogen dioxide (tropNO2), total column nitrogen dioxide (totNO2), and total column formaldehyde (totHCHO).
For Pandora the totNO2 product is a single measure of the total columns.
For TEMPO and TropOMI, the totNO2 product is the sum of tropNO2 and stratospheric NO2 that are separately retrieved.
Data Filtering
All data uses the version 3 (v3) TEMPO data products until 2025-09-07 when the algorithm was updated to v4.
For all analysis, all TEMPO data has been filtered for effective cloud fraction less than 0.15 based on SAO recommendation at the GeoXO ACX May 2025 meeting.
All data has also been filtered for high quality and having solar zenith angle less than 70 degrees.
The notable exceptions are when evaluating by effective cloud (no cloud filtering) or as a function of solar zenith angle (no angle filtering).
Cosampling
Pandora intersections are any TEMPO pixel that overlaps a 0.03-degree radius. Only intersections within 15 minutes of a TEMPO measurement are used.
TropOMI intersections are any TropOMI pixel that overlaps a TEMPO pixel with a region.
TropOMI regions have two types: Pandora sites or Non-attainment Area (NAA). TropOMI at Pandora sites are sampled within a 0.1-degree box around the site.
NAA use lat/lon boxes that contain the area, but may be substantially larger than the area.
Compared to Pandora sites, the NAA are larger and include more pixels.
The NAA have more area in the West, so the time-series including all sites are skewed by the western performance.
By comparison, the Pandora are more in the East.
As a result, the NAA region analysis of TropOMI should not be compared to the Pandora analysis at Pandora sites.
Statistical Analyses
All statistics are applied to samples either from all sites pooled or by each site. Within those groupings, statistical analyses are also applied withing groupings:
- month
- week
- solar zenith angle bin
- local standard hour of day
- TEMPO value bins
The statistics applied to each grouping include:
- count by bin
- correlation (R)
- Index of Agreement (IOA)
- Mean Bias (MB)
- Mean Absolute Bias (MB)
- Root Mean Square Error
- Least Squares Linear (LSQ) Regression (slope, intercept)
- Deming Regression (slope, intercept)
Statistics like MB, MAB, and RMSE are also shown as percents by normalizing to the reference dataset mean.
Citation
This dashboard is developed using the same techniques discussed in the TEMPO Validation Report (doi:
10.5067/doc/tempo/L2TraceGasValidationAssessment/V1.0).