TEMPO Validation Appendices

TropOMI (OFFL) vs TEMPO totHCHO

Barron H. Henderson (US EPA)

TropOMI (OFFL) vs TEMPO totHCHO

generated by: Barron H. Henderson
institution: US EPA
last updated: 2025-12-09T02-0500

1: Report Description

This report has plots organized by analysis region for TropOMI (OFFL) totHCHO. All data uses the version 3 (v3) TEMPO data products. Except when evaluating the effect of cloud fraction, all TEMPO data has been filtered for effective cloud fraction less than 0.15 based on SAO recommendation at the GeoXO ACX May meeting. All data has also been filtered for high quality and having solar zenith angle less than 70 degrees

TropOMI intersections are any TropOMI pixel that overlaps a TEMPO pixel. Statistics (mean, std, quantiles) are all based on all intersections within the region.

TropOMI intersections include both Pandora locations and Nonattainment Areas (NAA). However, the NAA are larger and include more pixels. The NAA have more area in the West, so the time-series including all sites are skewed by the western performance. By comparison, the Pandora are more in the East, so the time-series are any TropOMI pixel that overlaps a TEMPO pixel. Statistics (mean, std, quantiles) are all based on all intersections within the region.

Use section headers to navigate by Headings to a specific analysis region.

2: Location Overview

Figures 2.1 and 2.2 show all the locations used within this report. Pandora stations analyses compare all valid pixels in a 0.2 degree bounding box around the instrument. Nonattainment Areas (NAA) analyses include valid pixels within the bounding box that contains the area.

All Pandora stations used for NO2 analysis are shown, but only stations with a solid marker are used for HCHO.
Figure 2.1: All Pandora stations used for NO2 analysis are shown, but only stations with a solid marker are used for HCHO.

Nonattainment Areas used in this analysis are represented by the bounding envelope that surrounds them.
Figure 2.2: Nonattainment Areas used in this analysis are represented by the bounding envelope that surrounds them.

This section shows plots for all sites

3: All Sites by month

Box (25%, 50%, 75%) and whisker (min/max) plots by month at All Sites.
Figure 3.1: Box (25%, 50%, 75%) and whisker (min/max) plots by month at All Sites.

Scatter plot medians by month at All Sites with linear regression fit. Each point has all pixels in a month and error bars represent the 25% to 75% range of those pixels.
Figure 3.2: Scatter plot medians by month at All Sites with linear regression fit. Each point has all pixels in a month and error bars represent the 25% to 75% range of those pixels.

Count, correlation (R), index of agreement (IOA), mean bias (MB), mean absolute bias (MAB), root mean squared error (RMSE) at All Sites by month. MB, MAB, and RMSE are also sown as percents normalized to the reference mean.
Figure 3.3: Count, correlation (R), index of agreement (IOA), mean bias (MB), mean absolute bias (MAB), root mean squared error (RMSE) at All Sites by month. MB, MAB, and RMSE are also sown as percents normalized to the reference mean.

4: All Sites by week

Box (25%, 50%, 75%) and whisker (min/max) plots by week at All Sites.
Figure 4.1: Box (25%, 50%, 75%) and whisker (min/max) plots by week at All Sites.

Box (25%, 50%, 75%) and whisker (min/max) plots by week at All Sites for average weekday.
Figure 4.2: Box (25%, 50%, 75%) and whisker (min/max) plots by week at All Sites for average weekday.

Box (25%, 50%, 75%) and whisker (min/max) plots by week at All Sites for average weekend.
Figure 4.3: Box (25%, 50%, 75%) and whisker (min/max) plots by week at All Sites for average weekend.

Scatter plot medians by week at All Sites with linear regression fit. Each point has all pixels in a week and error bars represent the 25% to 75% range of those pixels.
Figure 4.4: Scatter plot medians by week at All Sites with linear regression fit. Each point has all pixels in a week and error bars represent the 25% to 75% range of those pixels.

Scatter plot medians by week at All Sites with linear regression fit for weekdays only. Each point has all pixels in a week and error bars represent the 25% to 75% range of those pixels.
Figure 4.5: Scatter plot medians by week at All Sites with linear regression fit for weekdays only. Each point has all pixels in a week and error bars represent the 25% to 75% range of those pixels.

Scatter plot medians by week at All Sites with linear regression fit weekends only. Each point has all pixels in a week and error bars represent the 25% to 75% range of those pixels.
Figure 4.6: Scatter plot medians by week at All Sites with linear regression fit weekends only. Each point has all pixels in a week and error bars represent the 25% to 75% range of those pixels.

5: All Sites by loc

Median by loc at All Sites for NAA.
Figure 5.1: Median by loc at All Sites for NAA.

Median Bias in #/cm2 by loc at All Sites for NAA.
Figure 5.2: Median Bias in #/cm2 by loc at All Sites for NAA.

Normalized Median Bias as a percent plots by loc at All Sites for NAA.
Figure 5.3: Normalized Median Bias as a percent plots by loc at All Sites for NAA.

Mean by loc at All Sites for NAA.
Figure 5.4: Mean by loc at All Sites for NAA.

Mean Bias in #/cm2 by loc at All Sites for NAA.
Figure 5.5: Mean Bias in #/cm2 by loc at All Sites for NAA.

Normalized Mean Bias as a percent plots by loc at All Sites for NAA.
Figure 5.6: Normalized Mean Bias as a percent plots by loc at All Sites for NAA.

Correlation at each loc at All Sites for NAA.
Figure 5.7: Correlation at each loc at All Sites for NAA.

Median by loc at All Sites for Pandora.
Figure 5.8: Median by loc at All Sites for Pandora.

Median Bias in #/cm2 by loc at All Sites for Pandora.
Figure 5.9: Median Bias in #/cm2 by loc at All Sites for Pandora.

Normalized Median Bias as a percent plots by loc at All Sites for Pandora.
Figure 5.10: Normalized Median Bias as a percent plots by loc at All Sites for Pandora.

Mean by loc at All Sites for Pandora.
Figure 5.11: Mean by loc at All Sites for Pandora.

Mean Bias in #/cm2 by loc at All Sites for Pandora.
Figure 5.12: Mean Bias in #/cm2 by loc at All Sites for Pandora.

Normalized Mean Bias as a percent plots by loc at All Sites for Pandora.
Figure 5.13: Normalized Mean Bias as a percent plots by loc at All Sites for Pandora.

Correlation at each loc at All Sites for Pandora.
Figure 5.14: Correlation at each loc at All Sites for Pandora.

Box (25%, 50%, 75%) and whisker (min/max) plots by loc at All Sites at NAA.
Figure 5.15: Box (25%, 50%, 75%) and whisker (min/max) plots by loc at All Sites at NAA.

Box (25%, 50%, 75%) and whisker (min/max) plots by loc at All Sites at Pandora.
Figure 5.16: Box (25%, 50%, 75%) and whisker (min/max) plots by loc at All Sites at Pandora.

Scatter plot medians by loc at All Sites with linear regression fit at NAA. Each point has all pixels in a loc and error bars represent the 25% to 75% range of those pixels.
Figure 5.17: Scatter plot medians by loc at All Sites with linear regression fit at NAA. Each point has all pixels in a loc and error bars represent the 25% to 75% range of those pixels.

Scatter plot medians by loc at All Sites with linear regression fit Pandora. Each point has all pixels in a loc and error bars represent the 25% to 75% range of those pixels.
Figure 5.18: Scatter plot medians by loc at All Sites with linear regression fit Pandora. Each point has all pixels in a loc and error bars represent the 25% to 75% range of those pixels.

Count by loc at All Sites at NAA.
Figure 5.19: Count by loc at All Sites at NAA.

Count by loc at All Sites at Pandora.
Figure 5.20: Count by loc at All Sites at Pandora.

Correlation (R) and index of agreement (IOA) by loc at All Sites at NAA.
Figure 5.21: Correlation (R) and index of agreement (IOA) by loc at All Sites at NAA.

Correlation (R) and index of agreement (IOA) by loc at All Sites at Pandora.
Figure 5.22: Correlation (R) and index of agreement (IOA) by loc at All Sites at Pandora.

Mean bias (MB), mean absolute bias (MAB), and root mean squared error (RMSE) by loc at All Sites at NAA.
Figure 5.23: Mean bias (MB), mean absolute bias (MAB), and root mean squared error (RMSE) by loc at All Sites at NAA.

Mean bias (MB), mean absolute bias (MAB), and root mean squared error (RMSE) by loc at All Sites at Pandora.
Figure 5.24: Mean bias (MB), mean absolute bias (MAB), and root mean squared error (RMSE) by loc at All Sites at Pandora.

Mean bias (MBP), mean absolute bias (MABP), and root mean squared error (RMSEP) as percents by loc at All Sites. Percents are normalized by the reference mean at NAA.
Figure 5.25: Mean bias (MBP), mean absolute bias (MABP), and root mean squared error (RMSEP) as percents by loc at All Sites. Percents are normalized by the reference mean at NAA.

Mean bias (MBP), mean absolute bias (MABP), and root mean squared error (RMSEP) as percents by loc at All Sites. Percents are normalized by the reference mean at Pandora.
Figure 5.26: Mean bias (MBP), mean absolute bias (MABP), and root mean squared error (RMSEP) as percents by loc at All Sites. Percents are normalized by the reference mean at Pandora.

6: All Sites by cld

Box (25%, 50%, 75%) and whisker (min/max) plots by cld at All Sites.
Figure 6.1: Box (25%, 50%, 75%) and whisker (min/max) plots by cld at All Sites.

Count, correlation (R), index of agreement (IOA), mean bias (MB), mean absolute bias (MAB), root mean squared error (RMSE) at All Sites by cld. MB, MAB, and RMSE are also sown as percents normalized to the reference mean.
Figure 6.2: Count, correlation (R), index of agreement (IOA), mean bias (MB), mean absolute bias (MAB), root mean squared error (RMSE) at All Sites by cld. MB, MAB, and RMSE are also sown as percents normalized to the reference mean.

7: All Sites by tempo

Count by tempo at All Sites.
Figure 7.1: Count by tempo at All Sites.

Mean bias (MB), mean absolute bias (MAB), and root mean squared error (RMSE) by tempo at All Sites.
Figure 7.2: Mean bias (MB), mean absolute bias (MAB), and root mean squared error (RMSE) by tempo at All Sites.

Mean bias (MBP), mean absolute bias (MABP), and root mean squared error (RMSEP) as percents by tempo at All Sites. Percents are normalized by the reference mean.
Figure 7.3: Mean bias (MBP), mean absolute bias (MABP), and root mean squared error (RMSEP) as percents by tempo at All Sites. Percents are normalized by the reference mean.

8: All Sites by sza

Box (25%, 50%, 75%) and whisker (min/max) plots by sza at All Sites.
Figure 8.1: Box (25%, 50%, 75%) and whisker (min/max) plots by sza at All Sites.

Scatter plot medians by sza at All Sites with linear regression fit. Each point has all pixels in a sza and error bars represent the 25% to 75% range of those pixels.
Figure 8.2: Scatter plot medians by sza at All Sites with linear regression fit. Each point has all pixels in a sza and error bars represent the 25% to 75% range of those pixels.

Count, correlation (R), index of agreement (IOA), mean bias (MB), mean absolute bias (MAB), root mean squared error (RMSE) at All Sites by sza. MB, MAB, and RMSE are also sown as percents normalized to the reference mean.
Figure 8.3: Count, correlation (R), index of agreement (IOA), mean bias (MB), mean absolute bias (MAB), root mean squared error (RMSE) at All Sites by sza. MB, MAB, and RMSE are also sown as percents normalized to the reference mean.

9: All Sites by lsth

Box (25%, 50%, 75%) and whisker (min/max) plots by lsth at All Sites.
Figure 9.1: Box (25%, 50%, 75%) and whisker (min/max) plots by lsth at All Sites.

Count, correlation (R), index of agreement (IOA), mean bias (MB), mean absolute bias (MAB), root mean squared error (RMSE) at All Sites by lsth. MB, MAB, and RMSE are also sown as percents normalized to the reference mean.
Figure 9.2: Count, correlation (R), index of agreement (IOA), mean bias (MB), mean absolute bias (MAB), root mean squared error (RMSE) at All Sites by lsth. MB, MAB, and RMSE are also sown as percents normalized to the reference mean.